In your particular case go for a wot spin on flat calm waters with the amount of boaters that will be riding that boat, check achieved wot rpm with a tach, compare numbers to your engine safe min-max wot range, can go from current in use prop maximizing pitch to suit your boating needs. This is not exact rocket science, must be dialed under trial and error.
Are you just asking or want to maximize a prop for your combo in which case more information is needed regarding boat type engine HP, prop size & pitch, number of passengers.
As an example while being at wot : If you select a prop that gives full wot rpm for that engine while being highly loaded, engine rpm will stay same, OTOH if you add more weight rpm will drop accordingly, if you reduce weight, rpm will raise accordingly. Once best pitch is dialed for that number of passengers you can run engine throughout the entire throttle range without worrying.
Happy Boating