Re: fuel octanes
By itself, higher octane does not mean higher head temperatures. There is only one reason for higher octane---to prevent pre-ignition and detonation. Pre-ignition and detonation will cause abnormal temperatures, even burn pistons. So you see, higher octane prevents those high temperatures, not causes them.
So, bottom line is if an engine is designed to require high octane fuel, you must use it or you will get pre-ignition and detonation. On the other hand, if an engine is designed to use lower octane there is no danger of pre-ignition and detonation, so there is no need of preventing it. There are a few outboards that do need high octane, mostly older ones. Read your owner's manual to see what you are supposed to be using. And don't be messing with the designed set-up (timing, carb jetting, and compression ratio, etc)
What I just said applies to non-computerized engines. Modern automobiles are a different story. The modern car has a computer controlled engine that actually de-tunes the engine if necessary to prevent damage from pre-ignition. In that case, low octane causes automatic de-tuning and lousy gas mileage.
Much of the misunderstanding comes from the old wives tale that high octane means higher energy content. That is a whole different topic.