Re: square or rectangular pontoons?
Round or an arch is the strongest shape there is, flat is the weakest.
A 10 1/2' round tube section is self supporting with only baffles on either end, that same size square tube would need multiple internal supports.
And it is easier to just run a tube through a roller and it is done where a square tube would need to have 3 sides formed on a break and the top welded on which would qualify it as a U tube so it would have to be filled with flotation foam.
So I would say it is both an engineering and manufacturing problem, too time consuming to build and not as strong as what is already being used.
There are several people making toons that aren't round but they are rare.
Basically round is the strongest easiest way to do it.