Vinyl Ester MEKP and safety

Dewpoint

Cadet
Joined
Jun 9, 2015
Messages
10
Hello, I am currently working on laying down the deck on my boat. Bigger project than I thought.... I am working with vinyl ester resin and MEKP as a hardener. I am using a half mask and bottom of the line safety goggles since MEKP in the eyes causes blindness!

The half mask has Honeywell 7581p100 filters and these seems to work as I do not smell product at all. But I still think I notice the effects through my eyes or maybe the filters aren't working for these chemicals. So I called Honeywell Safety Products and they said that they don't offer a mask that works with Vinyl Ester resin, or that they simply don't list that chemical with a recommended filter.

So I asked about the MEKP (Methyl Ethyl Ketone Peroxide) and they said no mask is necessary below .2 ppm (parts per million) and from .2 to 200 ppm requires a mask with an outside air supply! They don't have a filter that will work! They also said that they can't make a recommendation anyways because I don't know the concentrations of chemicals that I am working with. How could I figure that out anyways?! The amount of product used to the "out gassing" it gives off is an unknown to me.

So I guess this will be the last time I work with Vinyl Ester resins? Am I harming myself by using this product?

As a side note, I went to a fiberglass repair shop for a few last minute yards of fiberglass cloth and the workers there were working with either vinyl ester or polyester resins without any protection at all, eye or air!

Side note two, this stuff does stink! My shop is well ventilated and everyone can still smell it at the street +-110 feet away from the doors. Poor neighbors.

Thoughts?
 

tpenfield

Moderator
Staff member
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Jul 18, 2011
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18,452
No wonder I can't see anymore :noidea:

You are using about 1% MEKP, which is 10,000 ppm. The chemical respirator, with some forced ventilation (fan) near the work area should keep the fumes down, so your eyes are not affected.

That stuff is like chemical warfare, but it is the 'bomb' for repair work. Good adhesion, long open time . . .
 
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Dewpoint

Cadet
Joined
Jun 9, 2015
Messages
10
Thanks for the info. I do use a fan and an exhaust fan at the ceiling but I do still feel a very slight sting in my eyes when I have to work close to the spread out resin. And I feel funny for a few hours afterwards...
 

ondarvr

Supreme Mariner
Joined
Apr 6, 2005
Messages
11,527
People that don't work with these products frequently will normally have a very low level of tolerance for the products, as in, even very low levels of of fumes will be more than enough to cause irritation and concern. The levels considered save in the work place would be intolerable by a person off the street, it's just that the odor I so easy to detect by the human nose.

These workers use the products every day for years on end and don't really show any adverse affects from the exposure, I'm not saying it's healthy for you, only that your brief exposure to rather low levels isn't going to be an issue. Wear the protective gear you have don't stress over it.
 
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