Another way water can enter gasoline is through absorption from the air. Water, in the form of water vapor, can dissolve in gasoline. The more humid the air, the faster the water vapor will dissolve in the gasoline. Due to chemical equilibrium, however, assuming a constant temperature, phase separation will never occur if the only source of water is from the air. Only enough water to saturate the fuel can enter the system, and no more. Water vapor, however, dissolves in gasoline very slowly, even at very high humidity. For example, at a constant temperature of 100 degrees F and relative humidity of 100%, it would take well over 200 days to saturate one gallon of gasoline in an open gasoline can (assuming the only source of water is water vapor from the air). Water absorption from the air is far slower at lower temperatures and humilities. (At temperature of 70 degrees and relative humidity of 70%, it would take over two years to saturate one gallon of conventional gasoline in the same gasoline can.) Again, oxygenated gasoline can hold more water than conventional gasoline, and would therefore take much longer to saturate with water.
Conclusion
Water phase separation in any gasoline is most likely to occur when liquid water comes in contact with the fuel. (Water in the form of moisture in the air will generally not cause phase separation.